|
|
|
|
|
|
Ask the Experts | |||||||
|
|||||||
February 29, 2024 - Updated October 22, 2012 - Originally Posted Solder Paste Alloy CheckWe have a production line that runs mainly leaded paste. We accidentally assembled boards using lead-free paste and they went through a leaded profile during reflow. The problem was not discovered in time and I now have mixed product. Is there any easy method to check which paste has been used? R.L. |
|||||||
Expert Panel Responses | |||||||
If the lead-free solder paste was processed through the leaded thermal profile you may end up with unreflowed solder paste as the temperature may not have been hot enough to reflow all the paste. You could also see some partial wetting of the solder on the terminations. The difference in melting temperature between the lead and lead-free is 32°C, from 183 to 215°C and since the leaded reflow process is about 220 225°C, this is where the partial reflow may exists. The easiest method to prevent this from occurring is training and separate control areas where the materials are stored. Don't store the material in the same fridge, buy a lead-free fridge. This forces people to go to a different storage area to get the lead free material. Vice President, Technical Director EPTAC Corporation At EPTAC Corporation, Mr. Lambert oversees content of course offerings, IPC Certification programs and provides customers with expert consultation in electronics manufacturing, including RoHS/WEEE and lead free issues. Leo is also the IPC General Chairman for the Assembly/Joining Process Committee.
The industry recommends XRF spectroscopy as a test for lead and other metal constituents in solder joints.Again it is important to insure the XRF is properly calibrated to give meaningful results about the lead percentage or any other element. If lead-free paste was used the solder joint cosmetics will also be different from 63/37, the joints will exhibit a rougher surface if examined at 10X. The surface coloration is also slightly different. It does take a little comparative assessment but it can be done. Senior Market Development Engineer Kester Mr. Biocca was a chemist with many years experience in soldering technologies. He presented around the world in matters relating to process optimization and assembly. He was the author of many technical papers delivered globally. Mr. Biocca was a respected mentor in the electronics industry. He passed away in November, 2014.
The best way to see which ones were run with lead free solder paste is to use an XRF analyzer calibrated for sensing Pb (Lead). Scan each board with the XRF tool and separate those that show a no-lead signature. Visually, you should also notice duller solder joints on the no-lead paste boards. President Round Rock Consulting Following a successful 20 year career within world class OEMs and EMS providers including Honeywell, Bull Electronics, IBM, Celestica and Plexus, James founded Round Rock Consulting a business consultancy focused on supporting OEMs and EMS providers with product realization strategies.
The easiest way to check the approximate alloy composition is through XRF (x-ray fluorescence) technology. This equipment can non-destructively analyze the surface of the metal and give you the information that you need. If you do not have access to an XRF machine, I would suggest trying to find an outside lab that can run some samples for you to determine the solder paste alloy used. General Manager - Electronic Assembly Americas DEK International Mr. Smith has been supporting customers in the electronics assembly industry since 1994. His expertise is focused on solder paste printing and reducing soldering defects. He holds a BS in Chemical Engineering and an MBA in Marketing. He has authored several papers in trade magazines and at industry conferences. He is an SMTA Certified Process Engineer.
The two biggest problems here are:
Process Engineer Astronautics Fritz's career in electronics manufacturing has included diverse engineering roles including PWB fabrication, thick film print & fire, SMT and wave/selective solder process engineering, and electronics materials development and marketing. Fritz's educational background is in mechanical engineering with an emphasis on materials science. Design of Experiments (DoE) techniques have been an area of independent study. Fritz has published over a dozen papers at various industry conferences.
There is an instrument called an XRF gun that could detect whether the paste used contains lead or is lead-free. The testing is relatively inexpensive. General Manager Trace Laboratories Renee has been with Trace and an IPC member for 16 years. She has managed all military and commercial PB qualification and conformance testing and training, as well as product qualification and testing in the areas of solder pastes, fluxes, solder masks, and conformal coat. She is the chairman of the IPC Testing and the IPC-J-STD-004 Flux Specification Committees and the Vice Chairman of the Assembly and Joining Committee. She has published more than a dozen papers and presented at numerous electronics conferences.
Use XRF (x-ray fluorescence) to look for Pb content. SME Production Technical Excellence Staff Lockheed Martin Subject matter expert in the field of electronics assembly and soldering.
Reader Comment
While the XRF test method discussed by the other experts is the gold standard by which other tests are measured, if all you need to know is which boards have leaded alloys applied then there is possibly an easier method (depending on the number of assemblies in question).
Jon Ashton. Vergent Products
I routinely use "Instant Lead Testing Swabs". These swabs consist of a cardboard tube with two glass vials inside which are broken to mix powder and liquid components to generate a liquid that turns bright pink in the presence of lead. They are simple to use and a positive test is easy to present to Management based on the color change. When using a chemical test such as this it is highly recommended that the residues be removed by a capable aqueous wash process. The test method also doesn't address the root cause of the defect so I agree with the other Experts on having a separate location for the different paste alloys (and possibly flux chemistries). Reader Comment
With all due respect to the experts, I believe they are over thinking this. XRF is a great tool for detecting minute amounts of an element in a solder joint. In this case, however, you are looking for the presence or absence of a large amount of of an element. Expensive XRF equipment is not needed. As Jon Ashton suggested, lead test strips are perfectly adequate for this job and at a fraction of the cost of purchasing an XRF unit.
David Leeper, Panasonic
|
|||||||
Submit A Comment | |||||||
Comments are reviewed prior to posting. You must include your full name to have your comments posted. We will not post your email address. |
Free Newsletter Subscription
Circuitnet is built for professionals who bear the responsibility of looking ahead, imagining the future, and preparing for it. Insert Your Email Address |
|
|
|
|